Analysis of power line communications for last-hop backhaul in small cells deployment

Publicado en: :(2019-04-05),(José A. Cortes, Francisco J. Cañete, Matías Toril, Luis Díez, Alicia García-Mozos, "Analysis of power line communications for last-hop backhaul in small cells deployment", in Proceedings of the IEEE International Symposium on Power Line Communications and its Applications, 2019.),yEditor(IEEE)The purpose of this work is to study the feasibility of using power line communications (PLC) over outdoor public lighting networks (OPLN) for last-hop backhaul in small cell deployment. The analysis is based on actual noise measurements performed in two OPLN in the city of Málaga (Spain) and on a bottom-up channel simulator, which has been designed according to the physical characteristics and the common practices in such kind of networks. Estimations of the bit-rate achieved by PLC systems following the ITU-T Rec. G.9960 (G.hn) standard, are performed and discussed. Results indicate that PLC is a promising solution for this application.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Design of Covalent Organic Frameworks for Methane Storage

We designed 14 new covalent organic frameworks (COFs), which are expected to adsorb large amounts of methane (CH_4) at 298 K and up to 300 bar. We have calculated their delivery uptake using grand canonical Monte Carlo (GCMC) simulations. We also report their thermodynamic stability based on 7.5 ns molecular dynamics simulations. Two new frameworks, COF-103-Eth-trans and COF-102-Ant, are found to exceed the DOE target of 180 v(STP)/v at 35 bar for methane storage. Their performance is comparable to the best previously reported materials: PCN-14 and Ni-MOF-74. Our results indicate that using thin vinyl bridging groups aid performance by minimizing the interaction methane-COF at low pressure. This is a new feature that can be used to enhance loading in addition to the common practice of adding extra fused benzene rings. Most importantly, this report shows that pure nonbonding interactions, van der Waals (vdW) and electrostatic forces in light elements (C, O, B, H, and Si), can rival the enhancement in uptake obtained for microporous materials derived from early transition metals

High H_2 Uptake in Li-, Na-, K-Metalated Covalent Organic Frameworks and Metal Organic Frameworks at 298 K

The Yaghi laboratory has developed porous covalent organic frameworks (COFs), COF102, COF103, and COF202, and metal–organic frameworks (MOFs), MOF177, MOF180, MOF200, MOF205, and MOF210, with ultrahigh porosity and outstanding H2 storage properties at 77 K. Using grand canonical Monte Carlo (GCMC) simulations with our recently developed first principles based force field (FF) from accurate quantum mechanics (QM), we calculated the molecular hydrogen (H2) uptake at 298 K for these systems, including the uptake for Li-, Na-, and K-metalated systems. We report the total, delivery and excess amount in gravimetric and volumetric units for all these compounds. For the gravimetric delivery amount from 1 to 100 bar, we find that eleven of these compounds reach the 2010 DOE target of 4.5 wt % at 298 K. The best of these compounds are MOF200-Li (6.34) and MOF200-Na (5.94), both reaching the 2015 DOE target of 5.5 wt % at 298 K. Among the undoped systems, we find that MOF200 gives a delivery amount as high as 3.24 wt % while MOF210 gives 2.90 wt % both from 1 to 100 bar and 298 K. However, none of these compounds reach the volumetric 2010 DOE target of 28 g H_2/L. The best volumetric performance is for COF102-Na (24.9), COF102-Li (23.8), COF103-Na (22.8), and COF103-Li (21.7), all using delivery g H_2/L units for 1–100 bar. These are the highest volumetric molecular hydrogen uptakes for a porous material under these thermodynamic conditions. Thus, one can obtain outstanding H_2 uptakes with Li, Na, and K doping of simple frameworks constructed from simple, cheap organic linkers. We present suggestions for strategies for synthesis of alkali metal-doped MOFs or COFs

Recent advances on simulation and theory of hydrogen storage in metal–organic frameworks and covalent organic frameworks

This critical review covers the application of computer simulations, including quantum calculations (ab initio and DFT), grand canonical Monte-Carlo simulations, and molecular dynamics simulations, to the burgeoning area of the hydrogen storage by metal–organic frameworks and covalent-organic frameworks. This review begins with an overview of the theoretical methods obtained from previous studies. Then strategies for the improvement of hydrogen storage in the porous materials are discussed in detail. The strategies include appropriate pore size, impregnation, catenation, open metal sites in metal oxide parts and within organic linker parts, doping of alkali elements onto organic linkers, substitution of metal oxide with lighter metals, functionalized organic linkers, and hydrogen spillover (186 references)

Application-layer Performance Analysis of PRIME in Smart Metering Networks

This paper assesses the performance of actual PRIME v1.3.6 and PRIME v1.4 systems when used for Smart Metering applications. The analysis is performed at the application level using the DLMS/COSEM stack. Hence, it considers performance indicators that are of practical interest for distribution system operators, such as the availability and the average time needed to read the energy load profile of all the meters. To this end, two test networks with 112 smart meters have been deployed in the laboratory (to ensure the stability of the network). In one of them all the Service Nodes communicate directly with the Base Node, while there exist up to 5 switching levels in the other tested network. First, the PRIME v1.3.6 system is evaluated, stressing the significant performance gain that can be obtained by implementing some MAC layer strategies, which are compatible with the specification but not specifically defined on it. Then,the improvement offered by the PRIME v1.4 system is assessed.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment

We determined the methane (CH_4) uptake (at 298 K and 1 to 100 bar pressure) for a variety of covalent organic frameworks (COFs), including both two-dimensional (COF-1, COF-5, COF-6, COF-8, and COF-10) and three-dimensional (COF-102, COF-103, COF-105, and COF-108) systems. For all COFs, the CH_4 uptake was predicted from grand canonical Monte Carlo (GCMC) simulations based on force fields (FF) developed to fit accurate quantum mechanics (QM) [second order Møller−Plesset (MP2) perturbation theory using doubly polarized quadruple-ζ (QZVPP) basis sets]. This FF was validated by comparison with the equation of state for CH_4 and by comparison with the experimental uptake isotherms at 298 K (reported here for COF-5 and COF-8), which agrees well (within 2% for 1−100 bar) with the GCMC simulations. From our simulations we have been able to observe, for the first time, multilayer formation coexisting with a pore filling mechanism. The best COF in terms of total volume of CH_4 per unit volume COF absorbent is COF-1, which can store 195 v/v at 298 K and 30 bar, exceeding the U.S. Department of Energy target for CH_4 storage of 180 v/v at 298 K and 35 bar. The best COFs on a delivery amount basis (volume adsorbed from 5 to 100 bar) are COF-102 and COF-103 with values of 230 and 234 v(STP: 298 K, 1.01 bar)/v, respectively, making these promising materials for practical methane storage

Cosmic Neutrinos as a Window to Departures from Special Relativity

We review the peculiarities that make neutrinos very special cosmic messengers in high-energy astrophysics, and, in particular, to provide possible indications of deviations from special relativity, as it is suggested theoretically by quantum gravity models. In this respect, we examine the effects that one could expect in the production, propagation, and detection of neutrinos, not only in the well-studied scenario of Lorentz Invariance Violation, but also in models which maintain, but deform, the relativity principle, such as those considered in the framework of Doubly Special Relativity. We discuss the challenges and the promising future prospects offered by this phenomenological window to physics beyond special relativity

Matter-antimatter asymmetry without departure from thermal equilibrium

We explore the possibility of baryogenesis without departure from thermal equilibrium. A possible scenario is found, though it contains strong constraints on the size of the $CPT$ violation ($CPTV$) effects and on the role of the $B$ (baryon number) nonconserving interactions which are needed for it.Comment: Revtex, 4page

Reaching the boundary between stellar kinematic groups and very wide binaries. IV. The widest Washington double star systems with rho > 1000 arcsec in Gaia DR3

Aims: With the latest Gaia DR3 data, we analyse the widest pairs in the Washington Double Star (WDS) catalogue with angular separations, $\rho$, greater than 1000 arcsec. Methods: We confirmed the pair's membership to stellar systems based on common proper motions, parallaxes, and (when available) radial velocities, together with the locii of the individual components in colour-magnitude diagrams. We also looked for additional closer companions to the ultrawide pairs, either reported by WDS or found by us with a new Gaia astrometric search. In addition, we determined masses for each star (and white dwarf) and, with the projected physical separation, computed the gravitational potential energy, |Ug*|, of the systems. Results: Of the 155159 pairs currently catalogued by WDS, there are 504 with $\rho$ > 1000 arcsec. Of these, only 2 ultrawide pairs have not been identified, 10 do not have any available astrometry, 339 have not passed a conservative filtering in proper motion or parallax, 59 are members of young stellar kinematic groups, associations or open clusters, and only 94 remain as bona fide ultrawide pairs in the galactic field. Accounting for the additional members at shorter separations identified in a complementary astrometric and bibliographic search, we found 79 new stars (39 reported, plus 40 not reported by WDS) in 94 ultrawide stellar systems. This sample is expanded when including new close binary candidates with large Gaia DR3 RUWE, $\sigma_{Vr}$, or a proper motion anomaly. Furthermore, the large fraction of subsystems and the non-hierarchical configurations of many wide systems with three or more stars is remarkable.Comment: Accepted to A&A. 38 Pages, 8 figures and 9 tables (4 tables online